First make sure your TV's software/firmware is fully updated. It will be in the service menus.
Make sure your PS4 is set to RGB limited since you are playing on a TV. I think the Auto setting would be fine.
On Samsungs, we calibrate under the Movie picture mode. You can still use Game mode if you want but Movie would look more accurate and realistic. Just make sure noise reduction settings are off. Also settings like dynamic contrast, black tone, and auto motion plus should be off (Whatever Game mode has off, turn it off in other modes too). Another mandatory thing is to set screen adjustment to Screen Fit. Sharpness on Samsungs should be near 0 so you are correct there.
All of the other settings require proper understanding of calibration. Since you have the AVS disc, you should be able to do a good basic calibration but you need to learn how to make those adjustments (brightness, contrast, color, tint).
Last edited by ZKACAL; 08-14-2014 at 11:01 PM.