Craigslist can be a great way to get rid of stuff that works (even nominally) - either offer it for free or for a relatively small price (you know, like $10-$20).
If you can't give it away (for whatever reason), please recycle it, even if you have to pay a small fee to do so. It's just the more appropriate solution, especially if we're talking about older equipment (you know, that pre-RoHS stuff that will leech all manners of hell into the ground). As mcnarus said, contacting your local government is probably a good idea if you're unsure where to go - the trash co may also be a resource.