Things can change between generations Samsung have become much more aggressive on their custom DLNA with the E series, I too have a C series model and it doesn't work with all servers, UPnP only servers seem to have the most trouble.
If the DNS-323 has Samsung E series compatibility then it must be some other networking issue. DLNA is such a weak standard the chain can break in many places, it could be bugs in the router or firewall interfering with the traffic.
Try starting with these settings
Router with IP of 192.168.1.1
DHCP range 192.168.1.2 to 50
UPnP enabled on the router
IGMP multicast enabled on the router
Router firmware up to date
Re-run the network setup on the Samsung after the above and try connecting to the NAS.