"Canned air" is not just air - it needs a propellant - a liquid with a low vapor pressure.
Some of the liquid vaporizes in the can, until the pressure equals the vapor pressure of the liquid. Then the vaporization stops - and you have a 2-phase mixture in the can, plus the air, hair spray
or whatever. When you press the valve on top, you open the path for the pressure to drive the contents
out. This also lowers the pressure and allows more of the liquid to vaporize to generate more pressure
to expel the contents - until you close the valve and establish equilibrium again.
Aerosal cans originally used Freon, the stuff that is in air conditioners. It had the desired vapor
pressure properties, and was basically inert and non-flammable.
However, then came the concern about the "ozone-hole" and Freon in cans was banned.
Aerosal cans now use propane and other flammable propellants.
For safety's sake, keep ALL aerosal cans away from flame or hot surfaces that could ignite the flammable
propellant!!!
Dr. Gregory Greenman
Physicist