As always, good advice from Andy above, but a few things to add ...
In the original measurements, it's clear that your subs are falling off rapidly below their tuning frequencies. You do NOT want to ask a ported sub to produce meaningful SPL below its tuning frequency. That greatly increases the risk of physically damaging the driver.
I would recommend changing the lower limit of your optimization range to 35Hz (limit of the "weaker" sub in this regard). The upper limit stays the same (or could be increased if desired). Be sure to change the "PEQ Parameter Limits" values for the Min and Max Center Frequency to match the new optimization range. You would do this AFTER addressing the measurement issues noted by Andy. Here's a video on taking measurements for MSO using REW. It's shown on the Mac but the process is the same on Windows. (Disclaimer: Those are my videos, but you already mentioned watching them so I don't feel awkward point you at another one.)
Use the Buttkickers to cover the frequencies below 35 Hz. You can run all of this off the miniDSP. Route the input signal to all three outputs (2 subs, 1 buttkicker). MSO filters will go on the output side for just the 2 sub outputs. The output side for the Buttkickers will need a low-pass filter to keep them from playing above 30-35 Hz. I'm not sure what slope is recommended. However, based on the way your subs roll off, I'd probably start with a 4th-order (24 dB/octave) LR filter. You can use the gain features of the miniDSP or the iNuke to fine-tune the feel of the Buttkickers (or keep them from bottoming out if that's happening).