First, a good solder joint is better than a good crimp joint is better than a bad solder joint. So make good solder joints.
For soldering crossovers together, the standard 40w radio shack iron is fine - don't bother with an expensive station for hobbyist work. If you have an electronics supply shop in town, go there and ask for one of their $10 or so irons, they will be better than the RS iron and they will have a wider selection of solder too. For XO work you want a fairly large tip on the iron because you'll be heating well heatsinked joints since XO's use fairly thick copper wire (14ga inductors and whatnot) and the big tip will get heat to the joint faster. FWIW I use a $500 Weller station at work, and the 40 watt radio shack iron at home for my speaker stuff. So trust me, cheap irons are fine.
Also, use standard 63/37 rosin core (RA or RMA type) solder. No need for fancier blends or silver solder. I used 60/40 for ages til I started my new job and switched to 63/37. I tried using some 60/40 a few weeks back for xo work and that plastic stage is a ***** once you're used to eutectic stuff.
Also, pick up a small thing of paste flux. If you have trouble getting solder to wet on a joint properly, smudge some onto it and then try. It'll fix a lot of problems if you've got any oxidation on wires.