You could make a window "plug" using compressed fiberglass panels like OC703, which would also act as a broadband absorber. Wrap the panels in your choice of Guilford of Maine fabric. Size the panel to fit snugly into the frame around the window to block out all the light. If you have any gaps, use inexpensive felt weather stripping around the panel to seal the gaps. If you want to make it removable, you can mount a handle to the panel to pull it out of the window frame when needed.