I'm gonna be different here...I recently upgraded my speakers and A/V receiver, and the first movie I watched afterwards was The Matador.
I'll be honest...not a lot of LFE. But when there was, it was pretty incredible. The storm scene at the very beginning (which involves lightning hitting a tree, and the tree crashing down) nearly made me crap my pants. It gave me flashbacks of the tornado that destroyed my house a little over a year ago while I was asleep inside...truly disturbing.
There were several other great LFE scenes, and some interesting music tracks, but I honestly can't think of any specifics at the moment. In some thread it was stated that the LFE was artifically boosted for this movie, and folks were complaining about it. I liked it, personally.
Another good one is Seabiscuit...the horses galloping will rattle your walls.